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In this process, the mixture of two liquids is heated to the boiling point and the vapor from one liquid condenses on a cooled surface from the other. An example is ethanol/water.
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The vapor and liquid phases have the same composition in an azeotrope.
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An azeotropic distillation performed in a laboratory is normally done in batches in a conventional fractional distillation column.
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The components of azetropes cannot be separated by fractional distillation.
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You can also break azeotropes by distillation at a different pressure.
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This happens.
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.